Document

1 / 7Revision: 10.12.2007 Replaces the version of: 10.12.2007 PDF date: 13.12.2007 Kaba Cleaner (Pumpspray)63'210 A/92 Safety data sheet
according to Regulation (EC) No 1907/2006, Annex II
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Identification of the substance or preparation
Kaba Cleaner (Pumpspray)
63'210 A/92
Use of the substance/preparation
Cleaning agent. Lubrocates and cleans all types of locks. Protects against corrosion. Without propellant gas.
Company/undertaking identification
Trichema AG, Lättichstrasse 4, CH-6341 Baar
Telephone +41 (0)768 02 02, Fax +41 (0)768 02 00
www.trichema.ch, info@trichema.ch
Distributor:Kaba AG, Mühlebühlstrasse 23, CH-8620 WetzikonTel.: +41 (0)44 931 61 11, Fax: +41 (0)44 931 63 85 E-mail address of the competent person: info@chemical-check.de, k.schnurbusch@chemical-check.de Emergency telephone
Advisory office in case of poisoning:
Tel.: Swiss Toxicological Information Centre, Zurich (STIC, 24h): Tel. 145 (outside of Switzerland: +41 44 251 51 51)
Telephone number of the company in case of emergencies:
Tel. ---
2. HAZARDS IDENTIFICATION
To people
See point 11 and 15.
Preparation is classified as hazardous in the sense of directive 1999/45/EC.
Product is highly flammable.
Possible build up of explosive/highly flammable vapour/air mixture.
Harmful: may cause lung damage if swallowed.
Repeated exposure may cause skin dryness or cracking.
Vapours may cause drowsiness and dizziness
To the environment
See point 12.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Hazardous to drinking water, on escape of even small quantities.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical name
content %
R-phrases
EINECS, ELINCS
Registration number (ECHA)
Naphtha (petroleum), hydrodesulfurized heavy 50 - 70 Naphtha (petroleum), hydrotreated light 1 - 20 Hydrocarbon waxes (petroleum), oxidized, Me esters, barium salts/Barium sulfonate/Alkyl benzene, mixture 1 - 10 2 / 7Revision: 10.12.2007 Replaces the version of: 10.12.2007 PDF date: 13.12.2007 Kaba Cleaner (Pumpspray)63'210 A/92 For complete wording of the R-phrases, refer to point 16.
4. FIRST AID MEASURES
4.1 Inhalation
Remove person from danger area.
Supply person with fresh air and consult doctor according to symptoms.
If the person is unconscious, place in a stable side position and consult a doctor.
Respiratory arrest - Artificial respiration apparatus necessary.
4.2 Eye contact
Remove contact lenses.
Wash thoroughly for several minutes using copious water. Seek medical help if necessary.
4.3 Skin contact
Wash thoroughly with soap and copious water - remove contaminated clothing immediately. If skin irritation occurs (redness etc.),
consult doctor.
4.4 Ingestion
Rinse the mouth thoroughly with water.
Do not induce vomiting - give copious water to drink. Consult doctor immediately.
Danger of aspiration.
In case of vomiting, keep head low so that the stomach content does not reach the lungs.
4.5 Special resources necessary for first aid
Indications for the physician:
Symptomatic treatment
In case of irritation of the lungs, perform first-aid with controlled-dosage aerosol dexamethasone.
Pulmonary oedema prophylaxis
Subsequent observation for pneumonia and pulmonary oedema.
5. FIRE-FIGHTING MEASURES
5.1 Suitable extinguishing media
CO2
Extinction powder
Water jet spray
Alcohol resistant foam
Cool container at risk with water.
5.2 Extinguishing media which shall not be used for safety reasons
High volume water jet
5.3 Special exposure hazards arising from the substance or preparation itself,
combustion products, resulting gases
In case of fire the following can develop:
Oxides of carbon
Oxides of sulphur
Toxic pyrolysis products.
Explosive vapour/air mixture
Dangerous vapours heavier than air.
In case of spreading near the ground, flashback to distance sources of ignition is possible.
5.4 Special protective equipment for fire-fighters
In case of fire and/or explosion do not breathe fumes.
Protective respirator with independent air supply
According to size of fire
Full protection, if necessary
5.5 Further information
Dispose of contaminated extinction water according to official regulations.
6. ACCIDENTAL RELEASE MEASURES
Refer to point 13. and for personal protection refer to point 8.
6.1 Personal precautions
Remove possible causes of ignition - do not smoke.
Ensure sufficient supply of air.
Avoid inhalation, and contact with eyes or skin.
If applicable, caution - risk of slipping.
6.2 Environmental precautions
3 / 7Revision: 10.12.2007 Replaces the version of: 10.12.2007 PDF date: 13.12.2007 Kaba Cleaner (Pumpspray)63'210 A/92 If leakage occurs, dam up.
Prevent surface and ground-water infiltration, as well as ground penetration.
Prevent from entering drainage system.
If accidental entry into drainage system occurs, inform responsible authorities.
6.3 Methods for cleaning up
Collect using absorbant material (e.g. Universal binding medium, sand, kieselguhr) and dispose of according to point 13.
Fill the absorbed material into lockable containers.
7. HANDLING AND STORAGE
7.1 Handling
Tips for safe handling:
See point 6.1
Ensure good ventilation.
Room ventilation also at ground level.
Avoid inhalation of the vapours.
Avoid contact with eyes or skin.
Keep away from sources of ignition - Do not smoke.
Do not use on hot surfaces.
Take measures against electrostatic charging, if appropriate.
Eating, drinking, smoking, as well as food-storage, is prohibited in work-room.
Wash hands before breaks and at end of work.
Observe directions on label and instructions for use.
Use working methods according to operating instructions.
7.2. Storage
Requirements for storage rooms and
containers:
Not to be stored in gangways or stair wells.
Store product closed and only in original packing.
Do not store with flammable or self-igniting materials.
Keep away from food, drink and animal feedingstuffs.
Special storage conditions:
See point 10
Observe special storage conditions (in Germany, e.g., in accordance with the regulations in the "Betriebssicherheitsverordnung").
Store in a well ventilated place.
Protect from direct sunlight and warming.
Store cool
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 Exposure limit values
Chemical Name
Naphtha (petroleum), hydrodesulfurized heavy Chemical Name
Chemical Name
WEL-TWA: 5 mg/m3 (oil mist mineral, ACGIH) WEL-STEL: 10 mg/m3 (oil mist mineral, ACGIH) Chemical Name
WEL-TWA = Workplace Exposure Limit - Long-term exposure limit (8-hour TWA (= time weighted average) reference period) EH40. AGW = "Arbeitsplatzgrenzwert" (workplace limit value, Germany). | WEL-STEL = Workplace Exposure Limit - Short-terme exposure limit (15-minute reference period). | BMGV = Biological monitoring guidance value EH40. BGW = "Biologischer Grenzwert" (biological limit value, Germany) | Other information: Sen = Capable of causing occupational asthma. Sk = Can be absorbed through skin. Carc = Capable of causing cancer and/or heritable genetic damage.
** = The exposure limit for this substance is repealed through the TRGS 900 (Germany) of January 2006 with the goal of revision.
8.2 Exposure controls
8.2.1 Occupational exposure controls
4 / 7Revision: 10.12.2007 Replaces the version of: 10.12.2007 PDF date: 13.12.2007 Kaba Cleaner (Pumpspray)63'210 A/92 Ensure good ventilation. This can be achieved by local suction or general air extraction.
If this is insufficient to maintain the concentration under the WEL or AGW values, suitable breathing protection should be worn.
Applies only if maximum permissible exposure values are listed here.
Respiratory protection:
If OES or MEL is exceeded.
Filter A2 P2 (EN 141)
At high concentrations:
Respiratory protection appliance (insulation device) (e.g. EN 137 or EN 138)
Hand protection:
Solvent resistant protective gloves (EN 374).
If applicable
Protective PVC gloves (EN 374)
Protective nitrile gloves (EN 374)
Protective Viton gloves (EN 374)
Protective hand cream recommended.
Eye protection:
Tight fitting protective goggles with side protection (EN 166).
Skin protection:
Protective working garments (e.g. safety shoes EN 344, long-sleeved protective working garments)
Additional information on hand protection - No tests have been performed.
Selection made for preparations according to the best available knowledge and information on the ingredients.
Selection of materials derived from glove manufacturer's indications.
Final selection of glove material must be made taking the breakthrough times, permeation rates
and degradation into account.
Selection of a suitable glove depends not only on the material but also on other quality characteristics
and varies from manufacturer to manufacturer.
In the case of preparations the resistance of glove materials cannot be calculated in advance
so it has to be tested before use. The exact breakthrough time of the glove material can be
requested from the protective glove manufacturer and must be observed.
8.2.2 Environmental exposure controls
n.av.
9. PHYSICAL AND CHEMICAL PROPERTIES
Product is not explosive.
Possible build up of explosive/highly flammable vapour/air mixture.
Vapour pressure: 10. STABILITY AND REACTIVITY
Conditions to avoid
See point 7
Stable when handled and stored correctly.
Heating, open flame, ignition sources
Materials to avoid
Avoid contact with strong oxidizing agents.
Avoid contact with strong alkalis.
Avoid contact with strong acids.
Hazardous decomposition products
No decomposition when used as directed.
11. TOXICOLOGICAL INFORMATION
Revision: 10.12.2007 Replaces the version of: 10.12.2007 PDF date: 13.12.2007 Kaba Cleaner (Pumpspray)63'210 A/92 Acute toxicity and immediate effects
Ingestion, LD50 rat oral (mg/kg):
Delayed and chronic effects
Sensitization:
Further information
The product was not tested.
Classification according to calculation procedure.
The following may occur:
Irritation of the eyes
Irritation of the respiratory tract
Coughing
Headaches
Dizziness
Effects/damages the central nervous system
Coordination disorders
With long-term contact:
Product removes fat
Drying of the skin.
Dermatitis (skin inflammation)
Ingestion:
Nausea
Vomiting
Danger of aspiration.
Oedema of the lungs
12. ECOLOGICAL INFORMATION
The product was not tested.
Water hazard class (Germany): Persistence and degradability:Hardly biodegradable *Behaviour in sewage plants: Isolate as much as possible with an oil separator.
According to the recipe, contains no AOX.
Aquatic toxicity: Mobility:Adsorption in ground.*Accumulation:Concentration in organisms possible. ** Naphtha (petroleum), hydrodesulfurized heavy 13. DISPOSAL CONSIDERATIONS
13.1. for the material / preparation / residue
EC disposal code no.:
The waste codes are recommendations based on the scheduled use of this product.
Owing to the user's specific conditions for use and disposal, other waste codes may be
allocated under certain circumstances. (2001/118/EC, 2001/119/EC, 2001/573/EC)
14 06 03 other solvents and solvent mixes
20 01 29 detergents containing dangerous substances
Recommendation:
Pay attention to local and national official regulations
E.g. suitable incineration plant.
13.2 for contaminated packing material
See point 13.1
Pay attention to local and national official regulations
Recommendation:
Empty container completely.
6 / 7Revision: 10.12.2007 Replaces the version of: 10.12.2007 PDF date: 13.12.2007 Kaba Cleaner (Pumpspray)63'210 A/92 Uncontaminated packaging can be recycled.
Dispose of packaging that cannot be cleaned in the same manner as the substance.
Do not perforate, cut up or weld uncleaned container.
Residues may present a risk of explosion.
15 01 02 plastic packaging15 01 04 metallic packaging 14. TRANSPORT INFORMATION
General statements
UN-Number:
Road/Rail-transport (ADR/RID)
Class/packing group:
UN 3295 HYDROCARBONS, LIQUID, N.O.S. (SPECIAL PROVISION 640D)Classification code: Transport by sea
IMDG-code:
HYDROCARBONS, LIQUID, N.O.S.
Naphtha (petroleum), hydrodesulfurized heavy
Transport by air
IATA:
3/-/II (class/secondary danger/packing group) Hydrocarbons, liquid, n.o.s.
Additional information:
Danger code and packing code on request.
15. REGULATORY INFORMATION
Classification according to Dangerous Product Regulations incl. EC Directives
(67/548/EEC and 1999/45/EC)
Symbols: F/Xn/NIndications of danger:Highly flammableHarmfulDangerous for the environmentR-phrases:11 Highly flammable.
51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
65 Harmful: may cause lung damage if swallowed.
66 Repeated exposure may cause skin dryness or cracking.
67 Vapours may cause drowsiness and dizziness.
S-phrases:2 Keep out of the reach of children.
9 Keep container in a well-ventilated place.
16 Keep away from sources of ignition - No smoking.
23.f Do not breathe vapour/spray.
24/25 Avoid contact with skin and eyes.
29/35 Do not empty into drains; dispose of this material and its container in a safe way.
33 Take precautionary measures against static discharges.
51 Use only in well-ventilated areas.
61 Avoid release to the environment. Refer to special instructions/safety data sheets.
62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.
Additions:Naphtha (petroleum), hydrodesulfurized heavyNaphtha (petroleum), hydrotreated lightObserve restrictions: Observe youth employment law (German regulation).
Observe law on protection of expectant mothers (German regulation).
Observe restrictive guidelines 76/769/EEC, 1999/51/EC, 1999/77/ECVOC (1999/13/EC): 16. OTHER INFORMATION
Revision: 10.12.2007 Replaces the version of: 10.12.2007 PDF date: 13.12.2007 Kaba Cleaner (Pumpspray)63'210 A/92 These details refer to the product as it is delivered.
Storage class VCI (Germany): The following phrases represent the prescribed R-phrases for the ingredients (designated in point 2).
10 Flammable.
51 Toxic to aquatic organisms.
53 May cause long-term adverse effects in the aquatic environment.
65 Harmful: may cause lung damage if swallowed.
65 Also harmful: may cause lung damage if swallowed.
66 Repeated exposure may cause skin dryness or cracking.
67 Vapours may cause drowsiness and dizziness.
11 Highly flammable.
52 Harmful to aquatic organisms.
38 Irritating to skin.
n.a. = not applicable / n.v., k.D.v. = n.av. = not available / n.g. = n.c. = not checked
WEL = Workplace Exposure Limit EH40, TWA = Long-term exposure limit (8-hour TWA (= time weighted average) reference
period), STEL = Short-terme exposure limit (15-minute reference period) / BMGV = Biological monitoring guidance value EH40
AGW = "Arbeitsplatzgrenzwert" (workplace limit value, Germany) / BGW = "Biologischer Grenzwert" (biological limit value, Germany)
VbF = Regulations for flammable liquids (Austria)
WGK = water hazard class (Germany) - WGK 3 = very hazardous, WGK 2 = hazardous, WGK 1 = slightly hazardous to water
VOC = Volatile organic compounds / AOX = Adsorbable organic halogen compounds
VwVwS = Administrative Order relating to substances hazardous to water (Germany)
The statements made here should describe the product with regard to the necessary safety precautions - they are
not meant to guarantee definite characteristics - but they are based on our present up-to-date knowledge.
No responsibility.
These statements were made by:
Chemical Check GmbH, Wöbbeler Straße 2-4, D-32839 Steinheim, Tel.: +49 5233 94 17 0, +49 1805-
CHEMICAL / +49 180 52 43 642, Fax: +49 5233 94 17 90, +49 180 50 50 455
by Chemical Check GmbH Gefahrstoffberatung. The copying or changing of this document
is forbidden except with consent of the Chemical Check GmbH Gefahrstoffberatung.

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