Chemwatch msds msds for house of kolor high gloss thinner ru-10

ChemWatch MSDS MSDS for HOUSE OF KOLOR HIGH GLOSS THINNER RU-101 HOUSE OF KOLOR HIGH GLOSS THINNER RU-101
ChemWatch Material Safety Data Sheet
CHEMWATCH 5090-74
Date of Issue: Tue 12-Aug-2003
STATEMENT OF HAZARDOUS NATURE
HAZARDOUS ACCORDING TO WORKSAFE AUSTRALIA CRITERIA.
SUPPLIER
SYNONYMS
SHIPPING NAME
Product Name: House of Kolor High Gloss Thinner RU-101 file:///C|/Temp/House%20of%20Kolor/5090-74.HTM (1 of 19) [25/Aug/03 8:46:23 AM] ChemWatch MSDS MSDS for HOUSE OF KOLOR HIGH GLOSS THINNER RU-101 The use of a quantity of material in an unventilated or confined space mayresult in increased exposure and an irritating atmosphere developingBefore starting consider control of exposure by mechanical ventilationUsed according to manufacturers directions.
For further information refer to the House of Kolor Technical Manual PHYSICAL DESCRIPTION/PROPERTIES
APPEARANCE
Clear colourless highly flammable liquid with a strong solvent odout; does not mix with water.
INGREDIENTS
HEALTH HAZARD
ACUTE HEALTH EFFECTS
SWALLOWED
file:///C|/Temp/House%20of%20Kolor/5090-74.HTM (2 of 19) [25/Aug/03 8:46:23 AM] ChemWatch MSDS MSDS for HOUSE OF KOLOR HIGH GLOSS THINNER RU-101 Central nervous system (CNS) depression may include nonspecific discomfort,symptoms of giddiness, headache, dizziness, nausea, anaesthetic effects, slowedreaction time, slurred speech and may progress to unconsciousness. Seriouspoisonings may result in respiratory depression and may be fatal.
Considered an unlikely route of entry in commercial/industrial environments Theliquid may produce considerable gastrointestinal discomfort and may be harmfulor toxic if swallowed. Ingestion may result in nausea, pain and vomiting. Vomitentering the lungs by aspiration may cause potentially lethal chemicalpneumonitis Evidence exists, or practical experience predicts, that the material may causesevere eye irritation in a substantial number of individuals and/or may producesignificant ocular lesions which are present twenty-four hours or more afterinstillation into the eye(s) of experimental animals. Eye contact may causesignificant inflammation with pain. Corneal injury may occur; permanentimpairment of vision may result unless treatment is prompt and adequate.
Repeated or prolonged exposure to irritants may produce conjunctivitis.
The material may produce severe irritation to the eye causing pronouncedinflammation. Repeated or prolonged exposure to irritants may produceconjunctivitis.
The liquid produces a high level of eye discomfort and is capable of causingpain and severe conjunctivitis. Corneal injury may develop, with possiblepermanent impairment of vision, if not promptly and adequately treated.
The liquid may produce eye discomfort and is capable of causing temporaryimpairment of vision and/or transient eye inflammation, ulceration Skin contact with the material may damage the health of the individual; systemiceffects may result following absorption.
The material may produce moderate skin irritation; limited evidence or practicalexperience suggests, that the material either: · produces moderate inflammation of the skin in a substantial number ofindividuals following direct contact and/or· produces significant, but moderate, inflammation when applied to the healthyintact skin of animals (for up to four hours), such inflammation being presenttwenty-four hours or more after the end of the exposure period.
Skin irritation may also be present after prolonged or repeated exposure; thismay result in a form of contact dermatitis (nonallergic). The dermatitis isoften characterised by skin redness (erythema) and swelling (oedema) which mayprogress to blistering (vesiculation), scaling and thickening of the epidermis.
At the microscopic level there may be intercellular oedema of the spongy layerof the skin (spongiosis) and intracellular oedema of the epidermis.
Repeated exposure may cause skin cracking, flaking or drying following normalhandling and use.
Entry into the blood-stream, through, for example, cuts, abrasions or lesions, file:///C|/Temp/House%20of%20Kolor/5090-74.HTM (3 of 19) [25/Aug/03 8:46:23 AM] ChemWatch MSDS MSDS for HOUSE OF KOLOR HIGH GLOSS THINNER RU-101 may produce systemic injury with harmful effects. Examine the skin prior to theuse of the material and ensure that any external damage is suitably protected.
The material may cause skin irritation after prolonged or repeated exposure andmay produce a contact dermatitis (nonallergic). This form of dermatitis is oftencharacterised by skin redness (erythema) and swelling the epidermis.
Histologically there may be intercellular oedema of the spongy layer(spongiosis) and intracellular oedema of the epidermis.
Inhalation of aerosols (mists, fumes), generated by the material during thecourse of normal handling, may be harmful.
The material may produce respiratory tract irritation. Symptoms of pulmonaryirritation may include coughing, wheezing, laryngitis, shortness of breath,headache, nausea, and a burning sensation.
Unlike most organs, the lung can respond to a chemical insult or a chemicalagent, by first removing or neutralising the irritant and then repairing thedamage (inflammation of the lungs may be a consequence).
The repair process (which initially developed to protect mammalian lungs fromforeign matter and antigens) may, however, cause further damage to the lungs(fibrosis for example) when activated by hazardous chemicals. Often, thisresults in an impairment of gas exchange, the primary function of the lungs.
Therefore prolonged exposure to respiratory irritants may cause sustainedbreathing difficulties.
.
Inhalation of vapours may cause drowsiness and dizziness. This may beaccompanied by narcosis, drowsiness, reduced alertness, loss of reflexes, lackof coordination and vertigo.
The main effects of simple aliphatic esters are narcosis and irritation andanaesthesia at higher concentrations. These effects become greater as themolecular weights and boiling points increase. Central nervous system depression, headache, drowsiness, dizziness, coma and neurobehavioral changes may also besymptomatic of overexposure. Respiratory tract involvement may produce mucousmembrane irritation, dyspnea, and tachypnea, pharyngitis, bronchitis,pneumonitis and, in massive exposures, pulmonary oedema (which may be delayed).
Gastrointestinal effects include nausea, vomiting, diarrhoea and abdominalcramps. Liver and kidney damage may result from massive exposures.
Prolonged exposure may cause headache, nausea and ultimately loss ofconsciousness.
If exposure to highly concentrated solvent atmosphere is prolonged this may leadto narcosis, unconsciousness, even coma and possible death.
CHRONIC HEALTH EFFECTS
Substance accumulation, in the human body, may occur and may cause some concernfollowing repeated or long-term occupational exposure.
Exposure to the material for prolonged periods may cause physical defects in thedeveloping embryo (teratogenesis).
Chronic solvent inhalation exposures may result in nervous system impairmentand liver and blood changes. [PATTYS].
Chronic toluene habituation occurs following intentional abuse (glue sniffing) file:///C|/Temp/House%20of%20Kolor/5090-74.HTM (4 of 19) [25/Aug/03 8:46:23 AM] ChemWatch MSDS MSDS for HOUSE OF KOLOR HIGH GLOSS THINNER RU-101 or from occupational exposure. Ataxia, incoordination and tremors of the handsand feet (as a consequence of diffuse cerebral atrophy), headache, abnormalspeech, transient memory loss, convulsions, coma, drowsiness, reduced colourperception, frank blindness, nystagmus (rapid, involuntary eye-movements),decreased hearing loss leading to deafness and mild dementia have all beenassociated with chronic abuse. Peripheral nerve damage, encephalopathy, giantaxonopathy electrolyte disturbances in the cerebrospinal fluid and abnormalcomputer tomographic (CT scans) are common amongst toluene addicts. Althoughtoluene abuse has been linked with kidney disease, this does not commonly appearin cases of occupational toluene exposures. Cardiac and haematological toxicityare however associated with chronic toluene exposures. Cardiac arrhythmia,multifocal and premature ventricular contractions and supraventriculartachycardia are present in 20% of patients who abused toluene-containing paints.
Previous suggestions that chronic toluene inhalation produced human peripheralneuropathy have been discounted. However central nervous system (CNS) depressionis well documented where blood toluene exceeds 2.2 mg%. Toluene abusers canachieve transient circulating concentrations of 6.5 mg%. Amongst workers exposedfor a median time of 29 years, to toluene, no subacute effects on neurastheniccomplaints and psychometric test results could be established. The prenataltoxicity of very high toluene concentrations has been documented for severalanimal species and man. Malformations indicative of specific teratogenicity havenot generally been found. Neonatal toxicity, described in the literature, takesthe form of embryo death or delayed foetal growth and delayed skeletal systemdevelopment. Permanent damage of children has been seen only when mothers havesuffered from chronic intoxication as a result of "sniffing".
FIRST AID
SWALLOWED
If spontaneous vomiting appears imminent or occurs, hold patient's head down,lower than their hips to help avoid possible aspiration of vomitus.
· If swallowed do NOT induce vomiting.
· If vomiting occurs, lean patient forward or place on left side (head-downposition, if possible) to maintain open airway and prevent aspiration.
· Observe the patient carefully.
· Never give liquid to a person showing signs of being sleepy or with reducedawareness; i.e. becoming unconscious.
· Give water to rinse out mouth, then provide liquid slowly and as much ascasualty can comfortably drink.
· Seek medical advice.
Avoid giving milk or oils.
Avoid giving alcohol.
If this product comes in contact with the eyes:· Wash out immediately with fresh running water.
· Ensure complete irrigation of the eye by keeping eyelids apart and away fromeye and moving the eyelids by occasionally lifting the upper and lower lids.
file:///C|/Temp/House%20of%20Kolor/5090-74.HTM (5 of 19) [25/Aug/03 8:46:23 AM] ChemWatch MSDS MSDS for HOUSE OF KOLOR HIGH GLOSS THINNER RU-101 · If pain persists or recurs seek medical attention.
· Removal of contact lenses after an eye injury should only be undertaken byskilled personnel.
If skin contact occurs:· Immediately remove all contaminated clothing, including footwear· Flush skin and hair with running water (and soap if available).
· Seek medical attention in event of irritation.
· If fumes or combustion products are inhaled remove from contaminated area.
· Lay patient down. Keep warm and rested.
· Prostheses such as false teeth, which may block airway, should be removed,where possible, prior to initiating first aid procedures.
· Apply artificial respiration if not breathing, preferably with a demand valveresuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR ifnecessary.
· Transport to hospital, or doctor.
ADVICE TO DOCTOR
Any material aspirated during vomiting may produce lung injury. Therefore emesis should not be induced mechanically or pharmacologically. Mechanical means should be used if it is considered necessary to evacuate the stomach contents; these include gastric lavage after endotracheal intubation. If spontaneous vomiting has occurred after ingestion, the patient should be monitored for difficult breathing, as adverse effects of aspiration into the lungs may be delayed up to -------------------------------------------------------------------------------------- -------------------------------------------------------------------------------------- · Establish a patent airway with suction where necessary.
· Watch for signs of respiratory insufficiency and assist ventilation as · Administer oxygen by non-rebreather mask at 10 to 15 l/min.
· Monitor and treat, where necessary, for pulmonary oedema .
· Monitor and treat, where necessary, for shock.
· DO NOT use emetics. Where ingestion is suspected rinse mouth and give up to 200 ml water (5 ml/kg recommended) for dilution where patient is able to swallow, has a strong gag reflex and does not drool.
-------------------------------------------------------------------------------------- file:///C|/Temp/House%20of%20Kolor/5090-74.HTM (6 of 19) [25/Aug/03 8:46:23 AM] ChemWatch MSDS MSDS for HOUSE OF KOLOR HIGH GLOSS THINNER RU-101 -------------------------------------------------------------------------------------- · Consider orotracheal or nasotracheal intubation for airway control in unconscious patient or where respiratory arrest has occurred.
· Positive-pressure ventilation using a bag-valve mask might be of use.
· Monitor and treat, where necessary, for arrhythmias.
· Start an IV D5W TKO. If signs of hypovolaemia are present use lactated Ringers solution. Fluid overload might create complications.
· Drug therapy should be considered for pulmonary oedema.
· Hypotension with signs of hypovolaemia requires the cautious administration of fluids. Fluid overload might create complications.
· Proparacaine hydrochloride should be used to assist eye irrigation.
-------------------------------------------------------------------------------------- -------------------------------------------------------------------------------------- · Laboratory analysis of complete blood count, serum electrolytes, BUN, creatinine, glucose, urinalysis, baseline for serum aminotransferases (ALT and AST), calcium, phosphorus and magnesium, may assist in establishing a treatment regime. Other useful analyses include anion and osmolar gaps, arterial blood gases (ABGs), chest radiographs and electrocardiograph.
· Positive end-expiratory pressure (PEEP)-assisted ventilation may be required for acute parenchymal injury or adult respiratory distress syndrome.
· Consult a toxicologist as necessary.
BRONSTEIN, A.C. and CURRANCE, P.L. EMERGENCY CARE FOR HAZARDOUS MATERIALS -------------------------------------------------------------------------------------- -------------------------------------------------------------------------------------- · Establish a patent airway with suction where necessary.
· Watch for signs of respiratory insufficiency and assist ventilation as · Administer oxygen by non-rebreather mask at 10 to 15 l/min.
· Monitor and treat, where necessary, for pulmonary oedema .
· Monitor and treat, where necessary, for shock.
· DO NOT use emetics. Where ingestion is suspected rinse mouth and give up to 200 ml water (5mL/kg recommended) for dilution where patient is able to swallow, has a strong gag reflex and does not drool.
-------------------------------------------------------------------------------------- -------------------------------------------------------------------------------------- · Consider orotracheal or nasotracheal intubation for airway control in unconscious patient or where respiratory arrest has occurred.
file:///C|/Temp/House%20of%20Kolor/5090-74.HTM (7 of 19) [25/Aug/03 8:46:23 AM] ChemWatch MSDS MSDS for HOUSE OF KOLOR HIGH GLOSS THINNER RU-101 · Consider intubation at first sign of upper airway obstruction resulting from · Positive-pressure ventilation using a bag-valve mask might be of use.
· Monitor and treat, where necessary, for arrhythmias.
· Start an IV D5W TKO. If signs of hypovolaemia are present use lactated Ringers solution. Fluid overload might create complications.
· Drug therapy should be considered for pulmonary oedema.
· Hypotension with signs of hypovolaemia requires the cautious administration of fluids. Fluid overload might create complications.
· Proparacaine hydrochloride should be used to assist eye irrigation.
-------------------------------------------------------------------------------------- -------------------------------------------------------------------------------------- · Laboratory analysis of complete blood count, serum electrolytes, BUN, creatinine, glucose, urinalysis, baseline for serum aminotransferases (ALT and AST), calcium, phosphorus and magnesium, may assist in establishing a treatment regime. Other useful analyses include anion and osmolar gaps, arterial blood gases (ABGs), chest radiographs and electrocardiograph.
· Positive end-expiratory pressure (PEEP)-assisted ventilation may be required for acute parenchymal injury or adult respiratory distress syndrome.
· Consult a toxicologist as necessary.
EMERGENCY CARE FOR HAZARDOUS MATERIALS EXPOSURE: 2nd Ed. 1994.
Following acute or short term repeated exposures to toluene: · Toluene is absorbed across the alveolar barrier, the blood/air mixture being 11.2/15.6 (at 37 degrees C.) The concentration of toluene, in expired breath, is of the order of 18 ppm following sustained exposure to 100 ppm. The tissue/blood proportion is 1/3 except in adipose where the proportion is 8/10.
· Metabolism by microsomal mono-oxygenation, results in the production of hippuric acid. This may be detected in the urine in amounts between 0.5 and 2.5 g/24 hr which represents, on average 0.8 gm/gm of creatinine. The biological half-life of hippuric acid is in the order of 1-2 hours.
· Primary threat to life from ingestion and/or inhalation is respiratory · Patients should be quickly evaluated for signs of respiratory distress (eg cyanosis, tachypnoea, intercostal retraction, obtundation) and given oxygen.
Patients with inadequate tidal volumes or poor arterial blood gases (pO2 <50 mm Hg or pCO2 > 50 mm Hg) should be intubated.
· Arrhythmias complicate some hydrocarbon ingestion and/or inhalation and electrocardiographic evidence of myocardial damage has been reported; intravenous lines and cardiac monitors should be established in obviously symptomatic patients. The lungs excrete inhaled solvents, so that hyperventilation improves clearance.
· A chest x-ray should be taken immediately after stabilisation of breathing and circulation to document aspiration and detect the presence of pneumothorax.
· Epinephrine (adrenaline) is not recommended for treatment of bronchospasm because of potential myocardial sensitisation to catecholamines. Inhaled cardioselective bronchodilators (e.g. Alupent, Salbutamol) are the preferred agents, with aminophylline a second choice.
file:///C|/Temp/House%20of%20Kolor/5090-74.HTM (8 of 19) [25/Aug/03 8:46:23 AM] ChemWatch MSDS MSDS for HOUSE OF KOLOR HIGH GLOSS THINNER RU-101 · Lavage is indicated in patients who require decontamination; ensure use.
These represent the determinants observed in specimens collected from a healthy worker exposed at the Exposure Standard (ES or TLV): o-Cresol in urine 0.5 mg/L End of shift B Hippuric acid in 1.6 g/g creatinine End of shift B, NS NS: Non-specific determinant; also observed after exposure to other material B: Background levels occur in specimens collected from subjects NOT exposed PRECAUTIONS FOR USE
EXPOSURE STANDARDS
No data for House of Kolor High Gloss Thinner RU-101.
EXPOSURE STANDARDS FOR MIXTURE
"Worst Case" computer-aided prediction of vapour components/concentrations: Composite Exposure Standard for Mixture (TWA) (mg/m³): 357.0094 mg/m³ If the breathing zone concentration of ANY of the components listed below is exceeded, "Worst Case" considerations deem the individual to be overexposed.
Component Breathing Zone ppm Breathing Zone mg/m³ Mixture Conc: INGREDIENT DATA
file:///C|/Temp/House%20of%20Kolor/5090-74.HTM (9 of 19) [25/Aug/03 8:46:23 AM] ChemWatch MSDS MSDS for HOUSE OF KOLOR HIGH GLOSS THINNER RU-101 TLV TWA: 150 ppm, 713 mg/m³; STEL: 200 ppm, 950 mg/m³ ES TWA: 150 ppm, 713 mg/m³; STEL: 200 ppm, 950 mg/m³ OES TWA: 150 ppm, 724 mg/m³; STEL: 200 ppm, 966 mg/m³ MAK Category I Peak Limitation: For local irritants Allows excursions of twice the MAK value for 5 minutes at a time, 8 times per shift.
MAK values, and categories and groups are those recommended within the Odour Threshold Value: 0.0063 ppm (detection), 0.038-12 ppm (recognition) IDLH Level: 1700 ppm (lower explosive limit) Exposure at or below the recommended TLV-TWA is thought to prevent significant irritation of the eyes and respiratory passages as well as narcotic effects. In light of the lack of substantive evidence regarding teratogenicity and a review of acute oral data a STEL is considered PEL: 8hr TWA 200 ppm ; Ceiling Conc: 300ppm ; Max excursion: 500 ppm for 10 ES TWA: 50 ppm, 191 mg/m³; STEL 150 ppm, 574 mg/m³ SKIN NOTE: This substance has been classified by the ACGIH as A4 NOT classifiable as OES TWA: 50 ppm, 191 mg/m³; STEL: 150 ppm, 574 mg/m³ SKIN MAK Category II Peak Limitation: For substances with systemic effects and with a half-life in humans ranging from two hours to shift-length.
Allows excursions of 5 times the MAK value, for 30 minutes (on average), twice MAK Group C: There is no reason to fear risk of damage to the developing embryo when MAK and BAT values are observed.
MAK values, and categories and groups are those recommended within the Odour Threshold Value: 0.16-6.7 (detection), 1.9-69 (recognition) NOTE: Detector tubes measuring in excess of 5 ppm, are available.
Exposure limits with "skin" notation indicate that vapour and liquid may be absorbed through intact skin. Absorption by skin may readily exceed vapour inhalation exposure. Symptoms for skin absorption are the same as for inhalation. Contact with eyes and mucous membranes may also contribute to overall exposure and may also invalidate the exposure standard.
High concentrations of toluene in the air produce depression of the central nervous system (CNS) in humans. Intentional toluene exposure (glue-sniffing) at maternally-intoxicating concentration has also produced birth defects. Foetotoxicity appears at levels associated with CNS narcosis and probably occurs only in those with chronic toluene-induced kidney failure. Exposure at or below the recommended TLV-TWA is thought to prevent transient headache and irritation, to provide a measure of safety for possible disturbances to human reproduction, the prevention of reductions in cognitive responses reported amongst humans inhaling file:///C|/Temp/House%20of%20Kolor/5090-74.HTM (10 of 19) [25/Aug/03 8:46:23 AM] ChemWatch MSDS MSDS for HOUSE OF KOLOR HIGH GLOSS THINNER RU-101 greater than 40 ppm, and the significant risks of hepatotoxic, behavioural and nervous system effects (including impaired reaction time and incoordination). Although toluene/ethanol interactions are well recognised, the degree of protection afforded by the TLV-TWA among PEL TWA: 1000 ppm, 2400 mg/m³ [OSHA Z1] TLV TWA: 500 ppm, 1188 mg/m³; STEL: 750 ppm, 1782 mg/m³ A4 NOTE: This substance has been classified by the ACGIH as A4 NOT classifiable as ES TWA: 500 ppm, 1185 mg/m³; STEL: 1000 ppm, 2375 mg/m³ OES TWA: 750 ppm, 1810 mg/m³; STEL: 1500 ppm, 3620 mg/m³ IDLH Level: 2500 ppm (lower explosive limit) MAK Category I Peak Limitation: For local irritants Allows excursions of twice the MAK value for 5 minutes at a time, 8 times per shift.
MAK Group IIc: Substances with MAK Values but no pregnancy risk group classification. These are substances which have been investigated but for which no information regarding possible damage to the foetus/embryo was found. Mention calls attention to the absence of adequate data.
MAK values, and categories and groups are those recommended within the Odour Threshold Value: 3.6 ppm (detection), 699 ppm (recognition) Saturation vapour concentration: 237000 ppm @ 20 C NOTE: Detector tubes measuring in excess of 40 ppm, are available.
Exposure at or below the recommended TLV-TWA is thought to protect the worker against mild irritation associated with brief exposures and the bioaccumulation, chronic irritation of the respiratory tract and headaches associated with long-term acetone exposures. The NIOSH REL-TWA is substantially lower and has taken into account slight irritation experienced by volunteer subjects at 300 ppm. Mild irritation to acclimatised workers begins at about 750 ppm - unacclimatised subjects will experience irritation at about 350-500 ppm but acclimatisation can occur rapidly. Disagreement between the peak bodies is based largely on the view by ACGIH that widespread use of acetone, without evidence of significant adverse health effects at higher concentrations, allows Half-life of acetone in blood is 3 hours which means that no adjustment for shift-length has to be made with reference to the standard 8 hour/day, 40 hours per week because body clearance occurs within any shift with low A STEL has been established to prevent excursions of acetone vapours that could cause depression of the central nervous system.
file:///C|/Temp/House%20of%20Kolor/5090-74.HTM (11 of 19) [25/Aug/03 8:46:23 AM] ChemWatch MSDS MSDS for HOUSE OF KOLOR HIGH GLOSS THINNER RU-101 TLV TWA: 100 ppm, 434 mg/m³; STEL: 150 ppm, 651 mg/m³ A4 NOTE: This substance has been classified by the ACGIH as A4 NOT classifiable as ES TWA: 80 ppm, 350 mg/m³; STEL: 150 ppm, 655 mg/m³ (Under review) OES TWA: 100 ppm, 441 mg/m³; STEL: 150 ppm, 662 mg/m³ skin Exposure limits with "skin" notation indicate that vapour and liquid may be absorbed through intact skin. Absorption by skin may readily exceed vapour inhalation exposure. Symptoms for skin absorption are the same as for inhalation. Contact with eyes and mucous membranes may also contribute to overall exposure and may also invalidate the exposure standard.
Odour Threshold Value: 20 ppm (detection), 40 ppm (recognition) NOTE: Detector tubes for o-xylene, measuring in excess of 10 ppm, are available commercially. (m-xylene and p-xylene give almost the same Xylene vapour is an irritant to the eyes, mucous membranes and skin and causes narcosis at high concentrations. Exposure to doses sufficiently high to produce intoxication and unconsciousness also produces transient liver and kidney toxicity. Neurologic impairment is NOT evident amongst volunteers inhaling up to 400 ppm though complaints of ocular and upper respiratory tract irritation occur at 200 ppm for 3 to 5 minutes.
Exposure to xylene at or below the recommended TLV-TWA and STEL is thought to minimise the risk of irritant effects and to produce neither significant narcosis or chronic injury. An earlier skin notation was deleted because percutaneous absorption is gradual and protracted and does not substantially contribute to the dose received by inhalation.
No exposure limits set by NOHSC or ACGIH CAUTION: This substance has been classified by the ACGIH as A3 Animal Carcinogen ES TWA: 100 ppm, 435 mg/m³; STEL: 125 ppm, 545 mg/m³ (Under review) OES TWA: 100 ppm, 441 mg/m³; STEL: 125 ppm, 552 mg/m³ Designated H in List of MAK values: Danger of cutaneous absorption.
Absorption of such substances through the skin can pose an incomparably larger danger of toxicity than their inhalation. To avoid health risks when handling such substances, meticulous cleaning of the skin, hair and clothing is MAK Category I Peak Limitation: For local irritants Allows excursions of twice the MAK value for 5 minutes at a time, 8 times per shift.
MAK Group D: Classification as to the effect of the substance on the developing embryo/foetus is not yet possible because although data may indicate a trend, they are not sufficient for a final evaluation.
MAK values, and categories and groups are those recommended within the file:///C|/Temp/House%20of%20Kolor/5090-74.HTM (12 of 19) [25/Aug/03 8:46:23 AM] ChemWatch MSDS MSDS for HOUSE OF KOLOR HIGH GLOSS THINNER RU-101 IDLH Level: 800 ppm (lower explosion limit) NOTE: Detector tubes for ethylbenzene, measuring in excess of 30 ppm, are Ethyl benzene produces irritation of the skin and mucous membranes and appears to produce acute and chronic effects on the central nervous system. Animal experiments also suggest the effects of chronic exposure include damage to the liver, kidneys and testes. In spite of structural similarities to benzene, the material does not appear to cause damage to the haemopoietic system. The TLV-TWA is thought to be protective against skin and eye irritation. Exposure at this concentration probably will not Subjects exposed at 200 ppm experienced transient irritation of the eyes; at 1000 ppm there was eye irritation with profuse lachrymation; at 200 ppm eye irritation and lachrymation were immediate and severe accompanied by moderate nasal irritation, constriction in the chest and vertigo; at 5000 ppm exposure produced intolerable irritation of the eyes and ENGINEERING CONTROLS
For flammable liquids and flammable gases, local exhaust ventilation or a process enclosure ventilation system may be required. Ventilation equipment Air contaminants generated in the workplace possess varying "escape" velocities which, in turn, determine the "capture velocities" of fresh circulating air required to effectively remove the contaminant.
solvent, vapours, degreasing etc., 0.25-0.5 m/s (50-100 f/min.) evaporating from tank (in still air).
aerosols, fumes from pouring 0.5-1 m/s (100-200 f/min.) direct spray, spray painting in shallow 1-2.5 m/s (200-500 f/min.) Within each range the appropriate value depends on: Lower end of the range Upper end of the range 1: Room air currents minimal or 1: Disturbing room air currents file:///C|/Temp/House%20of%20Kolor/5090-74.HTM (13 of 19) [25/Aug/03 8:46:23 AM] ChemWatch MSDS MSDS for HOUSE OF KOLOR HIGH GLOSS THINNER RU-101 2: Contaminants of low toxicity or of 2: Contaminants of high toxicity 3: Intermittent, low production. 3: High production, heavy use 4: Large hood or large air mass in 4: Small hood-local control only Simple theory shows that air velocity falls rapidly with distance away from the opening of a simple extraction pipe. Velocity generally decreases with the square of distance from the extraction point (in simple cases). Therefore the air speed at the extraction point should be adjusted, accordingly, after reference to distance from the contaminating source. The air velocity at the extraction fan, for example, should be a minimum of 1-2 m/s (200-400 f/min.) for extraction of solvents generated in a tank 2 meters distant from the extraction point. Other mechanical considerations, producing performance deficits within the extraction apparatus, make it essential that theoretical air velocities are multiplied by factors of 10 or more when extraction systems are installed or PERSONAL PROTECTION
Contact lenses pose a special hazard; soft lenses may absorb irritants and all lenses concentrate them. DO NOT wear contact lenses.
HANDS/FEET
Wear chemical protective gloves, eg. PVC.
Wear safety footwear or safety gumboots, eg. Rubber PVC protective suit may be required if exposure severe.
Ensure there is ready access to a safety shower.
RESPIRATOR
Respiratory protection may be required when ANY "Worst Case" vapour-phase file:///C|/Temp/House%20of%20Kolor/5090-74.HTM (14 of 19) [25/Aug/03 8:46:23 AM] ChemWatch MSDS MSDS for HOUSE OF KOLOR HIGH GLOSS THINNER RU-101 concentration is exceeded (see Computer Prediction in "Exposure Standards").
Protection Factor Half-Face Respirator Full-Face Respirator * - Continuous-flow; ** - Continuous-flow or positive pressure demand The local concentration of material, quantity and conditions of use determine the type of personal protective equipment required. For further information consult site specific CHEMWATCH data (if available), or your Occupational SAFE HANDLING
STORAGE AND TRANSPORT
SUITABLE CONTAINER
Packing as supplied by manufacturer. Plastic containers may only be used ifapproved for flammable liquid. Check that containers are clearly labelled andfree from leaks.
· For low viscosity materials (i) : Drums and jerry cans must be of thenon-removable head type. (ii) : Where a can is to be used as an inner package,the can must have a screwed enclosure.
· For materials with a viscosity of at least 2680 cSt. (23 deg. C)· For manufactured product having a viscosity of at least 250 cSt. (23 deg. C)· Manufactured product that requires stirring before use and having a viscosityof at least 20 cSt (25 deg. C)(i) : Removable head packaging;(ii) : Cans with friction closures and(iii) : low pressure tubes and cartridges may be used.
· Where combination packages are used, and the inner packages are of glass,there must be sufficient inert cushioning material in contact with inner andouter packages· In addition, where inner packagings are glass and contain liquids of packinggroup I there must be sufficient inert absorbent to absorb any spillage, unlessthe outer packaging is a close fitting moulded plastic box and the substancesare not incompatible with the plastic.
STORAGE INCOMPATIBILITY
file:///C|/Temp/House%20of%20Kolor/5090-74.HTM (15 of 19) [25/Aug/03 8:46:23 AM] ChemWatch MSDS MSDS for HOUSE OF KOLOR HIGH GLOSS THINNER RU-101 STORAGE REQUIREMENTS
· Store in original containers in approved flame-proof area.
· No smoking, naked lights, heat or ignition sources.
· DO NOT store in pits, depressions, basements or areas where vapours may betrapped.
· Keep containers securely sealed.
· Store away from incompatible materials in a cool, dry well ventilated area.
· Protect containers against physical damage and check regularly for leaks.
· Observe manufacturer's storing and handling recommendations.
TRANSPORTATION
Class 3 - Flammable liquids shall not be loaded in the same vehicle or packed inthe same vehicle or packed in the same freight container with:Class 1 - Explosives;Class 2.1 - Flammable gases (where both flammable liquids and flammable gasesare in bulk);Class 2.3 - Poisonous gases;Class 4.2 - Spontaneously combustible substances;Class 5.1 - Oxidising agents;Class 5.2 - Organic peroxides;Class 7 - Radioactive substances.
SPILLS AND DISPOSAL
MINOR SPILLS
· Remove all ignition sources.
· Clean up all spills immediately.
· Avoid breathing vapours and contact with skin and eyes.
· Control personal contact by using protective equipment.
· Contain and absorb small quantities with vermiculite or other absorbentmaterial.
· Wipe up.
· Collect residues in a flammable waste container.
MAJOR SPILLS
· Clear area of personnel and move upwind.
· Alert Fire Brigade and tell them location and nature of hazard.
· May be violently or explosively reactive.
· Wear breathing apparatus plus protective gloves.
· Prevent, by any means available, spillage from entering drains or watercourse.
· Consider evacuation (or protect in place).
· No smoking, naked lights or ignition sources.
file:///C|/Temp/House%20of%20Kolor/5090-74.HTM (16 of 19) [25/Aug/03 8:46:23 AM] ChemWatch MSDS MSDS for HOUSE OF KOLOR HIGH GLOSS THINNER RU-101 · Increase ventilation.
· Stop leak if safe to do so.
· Water spray or fog may be used to disperse /absorb vapour.
· Contain spill with sand, earth or vermiculite.
· Use only spark-free shovels and explosion proof equipment.
· Collect recoverable product into labelled containers for recycling.
· Absorb remaining product with sand, earth or vermiculite.
· Collect solid residues and seal in labelled drums for disposal.
· Wash area and prevent runoff into drains.
· If contamination of drains or waterways occurs, advise emergency services.
EMERGENCY RESPONSE PLANNING GUIDLINES (ERPG)
The maximum airborne concentration below which it is believed that nearly all individuals could be exposed for up to one hour WITHOUT experiencing or developinglife-threatening health effects is 1000 ppmirreversible or other serious effects or symptomswhich could impair an individual's ability to take protective action is 300 ppmother than mild, transient adverse effectswithout perceiving a clearly defined odour is 50 ppmAmerican Industrial Hygiene Association (AIHA) DISPOSAL
· Recycle wherever possible.
· Consult manufacturer for recycling options or consult local or regional wastemanagement authority for disposal if no suitable treatment or disposal facilitycan be identified.
· Dispose of by: Burial in a licenced land-fill or Incineration in a licencedapparatus (after admixture with suitable combustible material)· Decontaminate empty containers. Observe all label safeguards until containersare cleaned and destroyed.
Puncture containers to prevent re-use and bury at an authorised landfill.
FIRE FIGHTERS' REPORT
EXTINGUISHING MEDIA
Alcohol stable foam.
Dry chemical powder.
BCF (where regulations permit).
Carbon dioxide.
Water spray or fog - Large fires only.
FIRE FIGHTING
file:///C|/Temp/House%20of%20Kolor/5090-74.HTM (17 of 19) [25/Aug/03 8:46:23 AM] ChemWatch MSDS MSDS for HOUSE OF KOLOR HIGH GLOSS THINNER RU-101 · Alert Fire Brigade and tell them location and nature of hazard.
· May be violently or explosively reactive.
· Wear breathing apparatus plus protective gloves.
· Prevent, by any means available, spillage from entering drains or watercourse.
· Consider evacuation (or protect in place).
· Fight fire from a safe distance, with adequate cover.
· If safe, switch off electrical equipment until vapour fire hazard removed.
· Use water delivered as a fine spray to control the fire and cool adjacentarea.
· Avoid spraying water onto liquid pools.
· Do not approach containers suspected to be hot.
· Cool fire exposed containers with water spray from a protected location.
· If safe to do so, remove containers from path of fire.
When any large container (including road and rail tankers) is involved in a fire,consider evacuation by 500 metres in all directions.
FIRE/EXPLOSION HAZARD
WARNING: In use may form flammable/ explosive vapour-air mixtures.
WARNING:· Can become highly flammable in use.
· Avoid evaporation.
· Liquid and vapour are highly flammable.
· Severe fire hazard when exposed to heat, flame and/or oxidisers.
· Vapour may travel a considerable distance to source of ignition.
· Heating may cause expansion or decomposition leading to violent rupture ofcontainers.
· On combustion, may emit toxic fumes of carbon monoxide (CO).
Combustion products include.
carbon dioxide (CO2).
other pyrolysis products typical of burning organic material.
Contains low boiling substance: Closed containers may rupture due to pressurebuildup under fire conditions.
FIRE INCOMPATIBILITY
Avoid contamination with oxidising agents i.e. nitrates, oxidising acids,chlorine bleaches, pool chlorine etc. as ignition may result CONTACT POINT
file:///C|/Temp/House%20of%20Kolor/5090-74.HTM (18 of 19) [25/Aug/03 8:46:23 AM] ChemWatch MSDS MSDS for HOUSE OF KOLOR HIGH GLOSS THINNER RU-101 This document is copyright. Apart from any fair dealing for the purposes ofprivate study, research, review or criticism, as permitted under the CopyrightAct, no part may be reproduced by any process without written permission fromCHEMWATCH. TEL (+61 3) 9572 4700.
file:///C|/Temp/House%20of%20Kolor/5090-74.HTM (19 of 19) [25/Aug/03 8:46:23 AM]

Source: http://www.smitsgroup.co.nz/images/objectimages/RU101.pdf